#729 added electrolyte diffusivity

Author: Scottmar93

input/parameters/lithium-ion/electrolytes/lipf6_Ecker2015/electrolyte_conductivity_Ecker2015.py

@@ -1,7 +1,7 @@
 import autograd.numpy as np
 
 
-def electrolyte_conductivity_Capiglia1999(c_e, T, T_inf, E_k_e, R_g):
+def electrolyte_conductivity_Ecker2015(c_e, T, T_inf, E_k_e, R_g):
     """
     Conductivity of LiPF6 in EC:DMC as a function of ion concentration [1, 2].
 

input/parameters/lithium-ion/electrolytes/lipf6_Ecker2015/electrolyte_diffusivity_Ecker2015.py

@@ -1,7 +1,7 @@
 import autograd.numpy as np
 
 
-def electrolyte_diffusivity_Capiglia1999(c_e, T, T_inf, E_D_e, R_g):
+def electrolyte_diffusivity_Ecker2015(c_e, T, T_inf, E_D_e, R_g):
     """
     Diffusivity of LiPF6 in EC:DMC as a function of ion concentration [1, 2].
 
@@ -34,7 +34,7 @@ def electrolyte_diffusivity_Capiglia1999(c_e, T, T_inf, E_D_e, R_g):
         Solid diffusivity
     """
 
-    D_c_e = 5.34e-10 * np.exp(-0.65 * c_e / 1000)
+    D_c_e = 2.4 * 10 ** (-10)
     arrhenius = np.exp(E_D_e / R_g * (1 / T_inf - 1 / T))
 
     return D_c_e * arrhenius

input/parameters/lithium-ion/electrolytes/lipf6_Ecker2015/parameters.csv

@@ -4,10 +4,10 @@ Name [units],Value,Reference,Notes
 # Electrolyte properties,,,
 Typical electrolyte concentration [mol.m-3],1000,,
 Cation transference number,0.26,,
-Electrolyte diffusivity [m2.s-1],ADD,, 
-Electrolyte conductivity [S.m-1],ADD,,
+Electrolyte diffusivity [m2.s-1],[function]electrolyte_diffusivity_Ecker2015,,
+Electrolyte conductivity [S.m-1],[function]electrolyte_conductivity_Ecker2015,,
 ,,,
 # Activation energies,,,
-Reference temperature [K],298.15,25C,
+Reference temperature [K],296.15,23C,
 Electrolyte diffusion activation energy [J.mol-1],1.71E+04,,
 Electrolyte conductivity activation energy [J.mol-1],1.71E+04,,